Chemistry MCQs for NEET — Practice Questions with Answers

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What is the value of E cell and equilibrium constant respectively for the reaction at $ 25 ^\circ C Fe_{(s)} + 2Ag ^ +_{(aq, 0.5 M)} \rightleftharpoons Fe^{2+} _{(aq, 0.1 M)} + 2Ag_{(s)} $ ?

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Which reaction would takes place spontaneously in forward direction at $ 25 ^\circ C if standard oxidation potenitials of Pt | I_{2(s)}| I ^ −, Cu | Cu^{2+}, Cr | Cr^{3+}, Zn | Zn^{2+}, Sn | Sn^{2+}, Pb | Pb^{2+}, Ag | Ag^ +, Fe | Fe^ {2+} $ are 0.54 V., − 0.34 V., 0.74 V., 0.76 V., 0.14 V., 0.13 V., −0.80 V., 0.77 V. respectively.

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How many gram of Ag will be obtained if 5.0 F quantity of electricity is passed through aqueous solution of $ AgNO_3$ ?

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If 15 Faraday quantity of electricity is passed through $ Al^{3+}_{(l)} $ solution then how many gram of Al metal will be obtained ? ( cell efficiency is 80 % .) ($ At.wt Al = 27 gm mol^{-1} $ )

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If 10 Faraday quantity of electricity is passed through molten NaCl during electrolysis 84 L of Cl2 gas is obtained at STP then what is the efficiency of the cell?

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Explanation

The efficiency of the cell is calculated by comparing the actual amount of gas obtained with the theoretical amount expected based on Faraday's law. If 10 Faraday of electricity produces 84 L of Clâ‚‚ gas, and the theoretical amount is 112 L (at STP), then the efficiency is (84/112) x 100% = 75%.

During electrolysis oif acqueous solution of NaCl with inert electrodes then at cathode instead of $ Na^+ reduction of H_2O $ takes place because .....................

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Explanation

During electrolysis of an aqueous NaCl solution with inert electrodes, H₂O is preferentially reduced at the cathode instead of Na⁺ ions because the reduction potential of Na⁺(aq) is very less (-2.71 V) compared to the reduction potential of H₂O (-0.83 V). The reaction with a higher reduction potential occurs more readily.

Select correct option for the given statements (where T = true anf F= false ) (i) if electrolysis of aqueous solution of $ CuSO_4$ is done with inert electrodes then blue colour of solution become faint. (ii) if electrolysis of aqueous solution of $ CuSO_4$ is done with inert electrodes then pH of the solution increases (iii) if electrolysis of aqueous solution of $ CuSO_4$ is done with active electrodes of Cu then weight of anode decreases (iv)if electrolysis of aqueous solution of $ CuSO_4$ is done with active electrodes of Cu then precious metals release from cathode.

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Select correct option for the given statements (where T = true anf F= false ) i) if electrolysis of dilute aqueous solution of NaCl is done with inert electrodes then pH of the solution increases. ii) if electrolysis of concentrated aqueous solution of NaCl is done with inert electrodes then at anode chloricne gas is obtained. iii) if electrolysis of dilute aqueous solution of NaCl is done with inert electrodes at cathode hydrogen gas is obtain. iv) if electrolysis of concentrated aqueous solution of NaCl is done with inert electrodes then on adding phenolphthalien to the solution becomes pink.

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Explanation

During electrolysis of dilute NaCl solution with inert electrodes, Na+ ions get reduced to Na at the cathode, forming NaOH which increases the pH. At the anode, Cl- ions get oxidized to Cl2 gas. This explains why statements (ii) and (iii) are true.

Select correct option for the given statements (where T = true anf F= false ) i) electrolysis of dilute aqueous solution of NaCl is done with inert electrodes then pH of the solution if increases. ii) if electrolysis of dilute aqueous solution of NaCl is done with inert electrodes then on adding methyl orange to the solution it becomes orange coloured. iii) if electrolysis of concentrated aqueous solution of NaCl is done with inert electrodes pOH of the solution increases. iv) if electrolysis of concentrated aqueous solution of NaCl is done with inert electrodes then the solution obtained turns red litmus to blue

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If at $ 50 ^\circ C temperature value of E^0_{ox} is + 0.83 V for the half cell Pt ∣ H_{2(g, 1.0, bar)} | OH ^- _{(aq)} then what is the value of ionic product of water at 50 ^ \circ C $ ?

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