Chemistry MCQs for NEET — Practice Questions with Answers

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60 ml 1M CH3COOH is mixed with 20 ml 1 M NaOH then pH of resulting solution will be

(Ka = 1.8 X 10-5, log1.8 = 0.25)

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Explanation

 

CH3COOH + NaOH         CH3COONa + H2O

At t=0    60ml 1M   20ml 1M         0          0

At t='t'   40ml 1M        0         20ml 1M     -

Now it is the acidic buffer solution.

pH=-logKa + logsaltacidpH=-log1.8 ×10-5log20×140×1pH=4.75 - 0.3pH=4.45

In which solvent, solubility of AgCl is maximum ?

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Explanation

In NH4OH, Ag+ form complex. Hence, Solubility of AgCl is maximum in NH4OH.

KpKc for the gaseous reaction:

I. 2A + 3B 2CII. 2A4BIII. A+B+2C 4D

Would be respectively:

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Explanation

Use, Kp=Kc(RT)ns

 

N2O4 dissociates as N2O4(g)2NO2(g) at 273 K and 2 atm pressure. The equilibrium mixture has a vapour density of 41. What will be the percentage degree of dissociation ?

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Explanation

Use, 

α=D-d(n-1)d

D=Theorotical vapour dessity

d= Observed apour density

n= No. of moles obtained after dissociation after one mole

α=46-41(2-1)41=0.122

% dissociation = 12.2%

On the adding inert gas to the equilibrium PCl5(g)PCl3(g) + Cl2(g) at constant pressure. The degree of dissociation will :

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Explanation

On adding inert gas at constant pressure, equilibrium shifts in tht direction where the number of moles are more.

The stability product constant Ksp of Mg(OH)2 is 9.0 X 10-12. If a solution is 0.010 M with respect to Mg2+ ion, waht is the maximum hydroxide ion concentration which could be present without causing the precipitation of Mg(OH)2

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Explanation

Mg(OH)2Mg2+ + 2OH-Ksp=[Mg2+] [OH-]29 × 10-12=0.01 × [OH-]2[OH-] =3 ×10-5M

Which may be added to one litre of water to act as a buffer

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Explanation

 

CH3COOH + NaOH CH3COONa + H2O

At t=0          1        0.5          0        0

Att t='t'       0.5        0         0.5      0.5

Now it is the acidic buffer solution.

Acoording to Bronsted-Lowry concept, the correct order of relative strength of bases follows the order

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Explanation

All weak acid has strong conjugate base and strong acid has weak conjugate base.

pOH of H2O is 7.0 at 298K. If water is heated at 350K, which of the following statement should be true ?

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Explanation

On heating dissociationof H2O increases. SO, [H+] as well s [OH-] increases and pH as well as pOH decreases.

In which case following equilibrium can't be established:

CaCO3(s) CaO(s) + CO2(g)

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Explanation

When pressure of CO2 gas greater than Kp then it can't shift in backward direction without CaO.

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