Chemistry MCQs for NEET — Practice Questions with Answers

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Solubility product constant (Ksp) of salts of types MX,MX2 and M3X at temperature T are 4.0 X 10-8, 3.2 X 10-14 and 2.7 X 10-15 respectively. Solublities(mol dm-3) of the salts at temperature T are the order:

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Explanation

For Mx, Ksp =S2

     For MX2, Ksp =4S3

     For M3X, Ksp =27S 4

Use the above formula and calculate the solubilities.

At 25°C the specific conductance of sturated solution of AgCl is 2.3 X 10-6 ohm-1cm-1. What will be the solubility of AgCl at 25°C if iconic conductances of Ag and Cl at infinite dilution are 61.9 and 76.3 ohm-1cm2mol-1 respectively.

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Explanation

 

 

 Solubility (S)=K×1000Λm                       =2.3×10-6×100061.9 + 76.3                       =2.3×10-3138.2                       =1.66 × 10-5mol/L

In the reaction, N2O4  2NO2α is that part of N2O4 which dissociates, then the number of moles at equilibrium will be:

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Explanation

4. N2O4 2NO2

       1         0     ---- at zero times

     1-α       2α   ---- at equilibrium

 No. of moles at equilibrium = 1-α+2α= 1+α

In which solution, AgCl has minimum solubility ?

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Explanation

In presence of common ion, solubility of salt decreases.

50 ml of HCl (pH=1) is mixed with another 100 ml of HCl (pH=2) then pH of resulting solution will be approximately

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Explanation

For pH=1,     N=10-1

For pH =2,    N=10-2

N1V1 + N2V2 = NV

10-1 X 50 + 10-2 X 100 = N X 150

N=4 X 10-2

pH =-log[H+] = -log4 X 10-2

pH=1.4

In a nitrating mixture (HNO3 + H2SO4), HNO3 acts as

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Explanation

 

The sulfuric acid in this mixture is sufficiently strong to protonate nitric acid, producing the nitronium ion (NO2+), which is the active species.

 

2H2SO4 + HNO3 → NO2+ + H3O+ + 2HSO4-

When aqueous NaCl solution is electrolysed using inert electrodes then pH of the solution

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Explanation

 

NaCl → Na+ + Cl−

H2O → H+ + OH−

Hydrogen & chloride ions discharge at negative & positive electrodes respectively,leaving behind sodium & hydroxide ions.These then combine to form sodium hydroxide,a strong base,

 

When a solution of acetic acid was titrated with NaOH, the pH of the solution when half of the acid, neutralised was 4.2. Dissociation constant of the acid is

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Explanation

For half neutralisation of weak acid from strong base,

pH=pKa

4.2=-log Ka

Ka=antilog of -4.2=6.31 X 10-5 

Among the following, the strongest Lewis acid is

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Explanation

due to least tendency to form BACK BONDING by Br atom.

Calculate the molar solublity of Fe(OH)2 at a pH of 8

[Ksp of Fe(OH)2 = 1.6 X 10-14]

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Explanation

pH=8, pOH = 6, [OH-] = 10-6

Fe(OH)2Fe2+ + 2OH-                      x            2xKsp = x ×[OH-]2x=1.6 × 10-14(10-6)2=0.016

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