Chemistry MCQs for NEET — Practice Questions with Answers

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NEET 2024

Match List I with List II.

List I (Reactions) List II (Reagents/Condition)
A. Bicyclohexyl → 2 cyclohexanone I. PhCOCl / Anhyd. AlCl₃
B. Benzene → diphenyl ketone II. CrO₃
C. Cyclohexanol → cyclohexanone III. KMnO₄ / KOH, Δ
D. Ar–CH₂CH₃ (with –COOK) → ozonolysis product IV. (i) O₃ (ii) Zn–H₂O

Choose the correct answer from the options given below:

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Explanation

A-III (KMnO₄/KOH), B-I (Friedel–Crafts acylation), C-II (CrO₃), D-IV (ozonolysis).

NEET 2024

Activation energy of any chemical reaction can be calculated if one knows the value of:

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Explanation

Arrhenius: $\ln(k_2/k_1) = (E_a/R)(1/T_1 - 1/T_2)$ — need $k$ at two $T$.

NEET 2024

The most stable carbocation among the following is:

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Explanation

(A) is a 3° carbocation with maximum hyperconjugation and inductive stabilisation.

NEET 2024

Given below are two statements:

Statement I: The boiling point of three isomeric pentanes follows the order n-pentane > isopentane > neopentane

Statement II: When branching increases, the molecule attains a shape of sphere. This results in smaller surface area for contact, due to which the intermolecular forces between the spherical molecules are weak, thereby lowering the boiling point.

In the light of the above statements, choose the most appropriate answer from the options given below:

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Explanation

Both standard NCERT facts — II is the correct explanation of I.

NEET 2024

Which one of the following alcohols reacts instantaneously with Lucas reagent?

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Explanation

Lucas test: 3° alcohols react instantaneously (immediate turbidity).

NEET 2024

The Henry's law constant ($K_H$) values of three gases (A, B, C) in water are $145$, $2\times 10^{-5}$ and $35$ kbar, respectively. The solubility of these gases in water follow the order:

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Explanation

Solubility $\propto 1/K_H$; B has the smallest $K_H$, A the largest.

NEET 2024

Which plot of $\ln k$ vs $\dfrac{1}{T}$ is consistent with Arrhenius equation? (Options are sketches of straight lines through the first quadrant: A — decreasing line with negative slope; B–D — increasing lines.)

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Explanation

$\ln k = \ln A - E_a/(RT)$ → slope $= -E_a/R < 0$.

NEET 2024

On heating, some solid substances change from solid to vapour state without passing through liquid state. The technique used for the purification of such solid substances based on the above principle is known as:

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Explanation

Direct solid → vapour transition is sublimation.

NEET 2024

Intramolecular hydrogen bonding is present in

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Explanation

Only in the ortho isomer are –OH and –NO₂ close enough to form an intramolecular H-bond.

NEET 2024

1 gram of sodium hydroxide was treated with 25 mL of $0.75$ M HCl solution, the mass of sodium hydroxide left unreacted is equal to:

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Explanation

25 mmol NaOH, 18.75 mmol HCl. Remaining NaOH = 6.25 mmol $\times$ 40 $=$ 250 mg.

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