Assertion : The ratio by volume of gaseous reactants and products is in agreement with their
molar ratio.
Reason : Volume of a gas is inversely proportional to the number of moles of a gas.
(C) at same temperature and Pressure.
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Assertion : The ratio by volume of gaseous reactants and products is in agreement with their
molar ratio.
Reason : Volume of a gas is inversely proportional to the number of moles of a gas.
(C) at same temperature and Pressure.
Assertion : Potassium and caesium are useful as electrodes in photoelectric cells.
Reason : Potassium and caesium, when irradiated with light, the light energy absorbed is sufficient to eject out the electron from an atom.
(A). Low ionisation energies of potassium and caesium.
If NaCl is doped with 10-4 mol % of SrCl2, the concentration of cation vacancies will be (NA = 6.023 x 1023 mol-1)
(c) Doping of NaCl with 10-4 mol % of SrCl2 means, 100 moles of NaCl are doped with 10-4 mol of SrCl2.
... 1 mol of NaCl is doped with
SrCl2 = 10-4/100 = 10-6 mole
As each Sr2+ ion introduces one cation vacancy.
... Concentration of cation vacancies
= 10-6 mol/mol of NaCl
= 10-6 x 6.023 x 1023 mol-1
= 6.023 x 1017 mol-1
CsCl crystallises in body-centred cubic lattice. If 'a' is its edge length then which of the following expressions is correct?
(C) For bcc if edge length is a, then
rCs+ + rCl- = (/2)*a
Metals have conductivity of the order of (ohm-1 cm-1):-
(b) The conductance order of metals is 106 to 108 ohm-1 cm-1.
Total volume of atoms present in a face centred cubic unit cell of a metal is ( r is atomic radius):
(D) Volume of atoms in cell = 4/3 r3 x n (n =4 for fcc)
= 4/3 x r3 x 4 = 16/3 r3
The mass of a unit cell of CsCl corresponds to:-
(c) A unit cell of CsCl having bcc structure consists of 8 atoms at the corner and one atom at centre.
Thus, no. of Cl- = 8x1/8 =1 and no. of Cs+ =1x1=1
Thus, no. of CsCl unit per unit cell = 1
With which one of the following elements silicon should be doped so as to give p-type of semiconductor?
(d) The n-type semiconductors are obtained when Si or Ge are doped with elements of group 15, eg, arsenic (As), while p-type semiconductors are obtained when Si or Ge are doped witlh traces of elements of group 13, ie, indium (In), boron (B).
Note : The conductivity of semiconductors increases with rise in temperature
The gas used in gas thermometer is:
the gas (preferably hydrogen or helium) is enclosed in a glass or fused-quartz bulb connected to a mercury manometer.
Which of the following phenomena could NOT be explained by Bohr's model of the atom?
The NCERT text states: 'Bohr’s model was also unable to explain the splitting of spectral lines in the presence of magnetic field (Zeeman effect) or an electric field (Stark effect).' Options 1, 2, and 4 are phenomena that Bohr's model successfully explained for hydrogenic atoms.
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