Amines MCQs for NEET — Chemistry Questions with Answers

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Assertion : Beryllium resembles aluminium.

Reason : : Charge / radius of Be2+ ion is nearly the same as that of the Al3+ ion.

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Explanation

(A) Beryllium and aluminium have diagonal relationship.

Assertion : Alkali metals dissolve in liquid ammonia and produce solvated cations and
solvated electrons

Reason : In concentrated solutions, the blue colour of the solutions of alkali metals in liquid ammonia, changes to bronze colour.

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Explanation

(B) M+x+yNH3MNH3x++eNH3y-

    Above 3M concentration, the solutions are no longer blue but are bronze/copper-bronze
            coloured with a metallic luster due to formation of metal ion clusters.

Sodium metal cannot be stored under-

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Explanation

(C). Na reacts with alcohol

      Na+C2H5OHC2H5ONa+12H2

Sodium looses its lustre on exposure to air due to formation of-

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Explanation

(A). In air, a layer of Na2O, NaOH and Na2CO3 is formed on its surface which loses its lustre.

      4Na+O22Na2O2H2O4NaOH2CO22Na2CO3+2H2O

Sodium oxide reacts with water violently forming NaOH. On heating above 400ºC, it produces

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Explanation

(C) Na2O+H2O2NaOH

     2Na2O400°CNa2O2+2Na

Alkaline earth metals form hydrated crystalline solids such as MgCl2.6H2O, CaCl2.6H2O. This is due to-

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Explanation

(C). The hydration energy of the ions of alkaline earth metals (M2+) is nearly 4 or 5 times greater than that of alkali metals because of their small size and increased charge.

Among the following compounds, which on heating do not produce N2?

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Explanation

(c) NH4Cl+ NaNO2→NH4NO2+NaCl
NH4NO2  N2↑ +2H2O

Ba(N3)2 →Ba+3N2↓ 
2NH4Cl+CaO→CaCl2+2NH3↑+H2O)

In which of the following compounds hydrolysis takes place through SN1 and SN2 mechanism respectively?

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Explanation

(a)   NF3+H2OS                            NCl3+H2OSN2

(b)    P4O10SNAE                      SiCl4SN2

(c)    SF4, TeF6Both SN2 

(d)    SiCl4, SiF4Both SN2

Incorrect statement about PH3 is :

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Explanation

(d)  PH3 (Lewis base) can react with B2H6 (Lewis acid).

 

Which of the following compound does not produce oxyacid of central atom on hydrolysis?

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Explanation

(d)    In NCl3 molecule, H2O molecule attacks on less electronegative Cl-atom 

         rather than central N-atom. NCl3+3H2ONH3+3HOCl 

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