Chemical Bonding and Atomic Structure MCQs for NEET — Chemistry Questions with Answers

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Assertion : Carbon has unique ability to form - multiple bonds with itself and with other

                  atoms of small size and high electronegativity.

Reason : Heavier elements of group 14th do not form - multiple bonds with itself because

               their atomic orbitals are too large and diffuse to have effective overlapping.

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Explanation

(B) Both Assertion and Reason are true statements but are different and reason is

      not true explanation of assertion. High electronegativity of atoms attached to carbon atom

      indirectly results into the contraction of the size of p-orbitals. As carbon atomic size is smaller

      and thus it has effective overlapping.

Assertion : NO+ and CN- both have same bond order and magnetism

Reason : NO+ and CN- are isoelectornic species.

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Explanation

(A) Number of electrons NO+ = 7+8-1 = 14

      Number of electrons CN- = 6+7+1 = 14

      Bond order = 10-42=3

      Both are diamagnetic.

Assertion : Crystals of hydrated calcium sulphate gypsum : CaSO4, 2H2O are soft and easily cleaved.

Reason : Crystals of anhydrous calcium sulphate anhydrite : CaSO4 are very hard and very difficult

               to cleave.

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Explanation

(B) Within the Ca2+/SO42- layers the ions are held together by strong electrovalent bonds. But

      these separated Ca2+/SO42- layers linked by relative weak H-bond. The weaker H-bonds and

      stretched along the layer of water molecules.

      Anhydride has a completely ionic structure involving only Ca2+ and SO42- ions.

When two atoms combine to form a molecule

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Explanation

To attain stability energy is released.

Compound having highest Melting Point :

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Explanation

As the size of cation increases polarising power decreases hence ionic character increases.

The diamagnetic species among the following is-

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Explanation

CO is diamagnetic as there are no odd electrons in the molecule.

Which of the statements are not true for AlCl3-

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Explanation

Anhydrous AlCl3 is covalent and is soluble in non polar solvents.

Valency expresses-

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Explanation

It is the basic definition.

Which of the following has maximum bond strength-

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Explanation

Bond order of O2+ is 2.5 which is maximum among all the species hence its bond strength will also be maximum.

Out of following which has maximum value of lattice energy

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Explanation

Due to small size of anion.

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