Chemical Bonding and Atomic Structure MCQs for NEET — Chemistry Questions with Answers

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Practicol dipal movement of HCl is 1.03D. If bond length of HCl is $1.275 A ^\circ $ than what will be the percentage of ionic nature in HCl ?

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Explanation

Theorectical dipole momentum $ H = q \times d [ 1 D = 1 \times 10 ^ {-18} esa cm ] $ $ = 4.8 \times 10 ^ {-10} \times 1.275 \times 10 ^ {-8} $ $ = 6.12 \times 10 ^ {-10} e.s.u cm $ $ = 6.12 D $ $ % of ionic character = { Practical ( \mu ) \over Theoretical (\mu) } $ $ = { 1.03 \over 6.12} \times 100 $ $ = 16.83 $ $ \approx 17 \% $

Which sentence is correct with respect to bond enthalpy ?

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Explanation

Bond enthalpy is affected by the number of nonbonding electron pairs on bonded atoms. Nonbonding electron pairs can cause repulsion, which weakens the bond and thus lowers the bond enthalpy.

How many numbers of bonding and nonbonding electron pairs in $CO_2$ ?

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Show paramagnetic compound given below.

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Explanation

KO2 (Potassium superoxide) is paramagnetic due to the presence of unpaired electrons in its molecular orbital configuration. The presence of a single unpaired electron in the antibonding π* orbital makes KO2 paramagnetic.

Which of the following does not possesses bond order as CO ?

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Explanation

The bond order of CO is 3. The bond order of NO+ is also 3, NO has a bond order of 2.5, N2 has a bond order of 3, and CN- has a bond order of 3. Therefore, NO (neutral) does not have the same bond order as CO.

Which of the following is the correct order for lone pair and bonding pair electrons ? Lp = Lone pair and Bp = Bonding pair

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Explanation

In VSEPR (Valence Shell Electron Pair Repulsion) theory, the repulsion between lone pairs (Lp) of electrons is greater than the repulsion between lone pair and bonding pair (Bp) of electrons, which in turn is greater than the repulsion between bonding pairs of electrons. Hence, the correct order is Lp-Lp > Lp-Bp > Bp-Bp.

Which theory is useful to determine geometrical structure of molecules ?

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Explanation

The VSEPR (Valence Shell Electron Pair Repulsion) theory is primarily used to determine the geometrical structure of molecules. It predicts the shape of individual molecules based on the extent of electron-pair electrostatic repulsion.

Which of the following has maximum bond angle ?

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Which of the following have equal bond order ?

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Explanation

The bond order of $O_2$ is 2, CN is 3, and $NO^+$ is also 3. Therefore, CN and $NO^+$ have equal bond orders.

The type of bond present in $CuSO_4 .5H_2O$

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