Chemical Thermodynamics MCQs for NEET — Chemistry Questions with Answers

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Which is not a spontaneous process?

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Explanation

(c) Heat cannot be itself pass from colder to hotter body.

All the naturally occurring processes, i.e., spontaneous proceed spontaneously in a direction which leads to:

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Explanation

(a) For a spontaneous process G=-ve or <0.

In which case entropy decreases?

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Explanation

3. In stretching of rubber band, entropy decreases because molecules are arranged in ordered form.

For exothermic reaction to be spontaneous (S=negative)

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Explanation

For spontaneous reaction, G should be -ve.

'The free energy change due to a reaction is zero when

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Explanation

 

At eqm, no net reaction takes place so no change in energy.

An ideal gas expands at a constant external pressure of 2.0 atmosphere by 20 litre and absorbs 10kJ of heat from surrounding. What is the change in internal energy of the system:-

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Explanation

U = q + W

      = q - PV = 10x1000 -2(20) x101.3 = 5948 J

The temperature of an ideal gas expansion increases in an:-

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Explanation

In adiabatic compression, work is converted into heat because the transfer of heat is not allowed.

36 ml of pure water takes 100 sec to evaporate from a vessel and heater connected to an electric source which delivers 806 watt. The Hvaporisation of H2O is:-

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Explanation

1 watt = 1 J/sec

Total heat supplied for 36 ml H2O = 806 x 100 =  80600 J

            Hvap. = 80600/36  x 18   = 40300 J/mol = 40.3 kJ/mol

5 moles of an ideal gas expands isothermally and irreversibly from a pressure of 10 atm to 1 atm against a constant external pressure of 1 atm. find the Wirr at 300 K:-

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Explanation

Wirr = -Pext[nRTP2-nRTP1]

Wirr = -1 x (5 x 8.314/1000 x 300) x(1 - 1/10)

       = -11.224 KJ

In the reaction at 300 K

H2(g) + Cl2(g)2HCl(g)       H°= -185 kJ

if 2 mol of H2 completely react with 2 mole of Cl2 to form HCl. What is U° for this reaction:-

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Explanation

 ng=0  fpr 2 mol (H2)   

    H°=U°U°=-185 x 2 = -370 kJ 

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