What is the meanfree path and collision frequency of a nitrogen molecule in a cylinder containing nitrogen at 2 atm and temperature $ 17 ^\circ C $ ? Take the radius of nitrogen molecule to be 1A . Molecular mass of nitrogen = 28 , $ k_B = 1.38 \times 10^{-23} JK^{-1} , 1 atm = 1.013 \times 10^5 Nm^{-2} $
$ \bar l = { k_B T \over \sqrt 2 \pi P d^2 } = { (1.38 \times 10^{-23}) (290) \over (\sqrt 2 )(3.14) ( 2.026 \times 10^{-5} ) (2 \times 10^{-10} )^2 }= 1.11 \times 10^{-7} m $ Collision Frequency = no. of collision per second = $ { \nu_{rms} \over l} = { 508.24 \over 1.11 \times 10^{-7} } = 4.58 \times 10^9 $ $ \left( \nu_{rms} = \sqrt { 3RT \over M_o } = \sqrt { (3) (8.314) (290 ) \over 28 \times 10^{-3}} = 508.24 ms^{-1} \right) $