Thermodynamics MCQs for NEET — Physics Questions with Answers

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A gas mixture consists of 2 moles of oxygen and 4 moles argon at temperature T. Neglecting all vibrational modes, the total internal energy of the system is 

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Explanation

Oxygen is diatomic gas, hence its energy of two moles =2×52RT=5RT

Argon is a monoatomic gas, hence its internal energy of 4 moles =4×32RT=6RT

Total Internal energy = (6 + 5)RT = 11RT

An ideal gas expands isothermally from a volume V1 to V2 and then compressed to original volume V1 adiabatically. Initial pressure is P1 and final pressure is P3. The total work done is W. Then -

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Work done by a system under isothermal change from a volume V1 to V2 for a gas which obeys Vander Waal's equation (Vβn)P+αn2V=nRT

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Explanation

According to given Vander Waal’s equation

P=nRTVnβαn2V2

Work done, W=V1V2PdV=nRTV1V2dVVnβαn2V1V2dVV2

=nRT[loge(Vnβ)]V1V2+αn21VV1V2

=nRTlogeV2nβV1nβ+αn2V1V2V1V2

The molar heat capacity in a process of a diatomic gas if it does a work of Q4 when a heat of Q is supplied to it is -

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Explanation

dU=CVdT=52RdT or dT=2(dU)5R …..(i)

From first law of thermodynamics

dU=dQdW=QQ4=3Q4.

Now molar heat capacity C=dQdT=Q2(dU)5R=5RQ23Q4=103R.

An insulator container contains 4 moles of an ideal diatomic gas at temperature T. Heat Q is supplied to this gas, due to which 2 moles of the gas are dissociated into atoms but temperature of the gas remains constant. Then

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Explanation

Q = ΔU = UfUi = [internal energy of 4 moles of a monoatomic gas + internal energy of 2 moles of a diatomic gas] – [internal energy of 4 moles of a diatomic gas]

=4×32RT+2×52RT4×52RT= RT

= RT

Note : (1) 2 moles of diatomic gas becomes 4 moles of a monoatomic gas when gas dissociated into atoms.

Internal energy of μ moles of an ideal gas of degrees of freedom F is given by U=f2μRT

f = 3 for a monoatomic gas and 5 for diatomic gas.

The volume of air increases by 5% in its adiabatic expansion. The percentage decrease in its pressure will be -

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Explanation

PVγ=K or PγVγ1dV+dP.Vγ=0

or dPP=γdVV or dPP×100=γdVV×100

= –1.4 × 5 = 7%

The temperature of a hypothetical gas increases to 2 times when compressed adiabatically to half the volume. Its equation can be written as

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Explanation

TVγ1 = constant

T1T2=V2V1γ1 or 12γ1=12

γ1=12 or γ=32

PV3/2 = constant

Two Carnot engines A and B are operated in succession. The first one, A receives heat from a source at T1 = 800 K and rejects to sink at T2 K. The second engine B receives heat rejected by the first engine and rejects to another sink at T3 = 300 K. If the work outputs of two engines are equal, then the value of T2 is -

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Explanation

ηA=T1T2T1=WAQ1ηB=T2T3T2=WBQ2

Q1Q2=T1T2×T2T3T1T2=T1T2

WA = WB

T2=T1+T32=800+3002=550K

When an ideal monoatomic gas is heated at constant pressure, fraction of heat energy supplied which increases the internal energy of gas, is 

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Explanation

For monoatomic gas

γ=CPCV=53 we know ΔQ=nCPΔT

and ΔU=nCVΔTΔUΔQ=CVCP=35

i.e. fraction of heat energy to increase the internal energy be 3/5.

When an ideal gas (γ = 5/3) is heated under constant pressure, then what percentage of given heat energy will be utilised in doing external work ?

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Explanation

ΔQ=ΔU+ΔWΔWΔQ=1ΔUΔQ=1nCVdTnCPdT

ΔWΔQ=1CVCP=135=25=0.4

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