Thermodynamics MCQs for NEET — Physics Questions with Answers

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Which one of the following gases possesses the largest internal energy?

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Explanation

U=n​fRT2

(U)N=56×10328×52R×300

and (U)Ar=6×10266×1023×32R×900(U)Ar<(U)N

Two samples A and B of a gas initially at the same pressure and temperature are compressed from volume V to V/2 (A isothermally and B adiabatically). The final pressure of A is 

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Explanation

A is compressed isothermally, hence

P1V=P2V2P2=2P1

and B is compressed adiabatically, hence

P1Vγ=P2V2γP2=(2)γP1

Since γ>1, hence P2'>P2 or P2<P'2

Initial pressure and volume of a gas are P and V respectively. First it is expanded isothermally to volume 4V and then compressed adiabatically to volume V. The final pressure of gas will be [Given : γ=1.5 ]-

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Explanation

In isothermal process P1V1=P2V2

or PV=P2×4V

P2=P4

In adiabatic process

P2V2γ=P3V3γ

P4×(4V)1.5=P2V1.5

P3=2P

A reversible engine converts one-sixth of the heat input into work. When the temperature of the sink is reduced by 62°C, the efficiency of the engine is doubled. The temperatures of the source and sink are -

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Explanation

Initially η=1T2T1=WQ=16  ...(i)

Finally η'=1T2'T1=1(T262)T1=1T2T1+62T1

=η+62T1 ....(ii)

It is given that η'=2η. Hence solving equation (i) and (ii)

T1=372K=99°C and T2=310K=37°C

An ideal gas expands in such a manner that its pressure and volume can be related by equation PV5/3 = constant. During this process, the gas is 

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Explanation

PV5/3= constant represents adiabatic equation.

So during the expansion of ideal gas internal energy of gas decreases and temperature falls.

P-V diagram of a diatomic gas is a straight line passing through origin. The molar heat capacity of the gas in the process will be -

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Explanation

P-V diagram of the gas is a straight line passing through origin. Hence PV or PV1= constant

Molar heat capacity in the process PVx=constant is 

C=Rγ1+R1x; Here γ=1.4 (For diatomic gas)

C=R1.41+R1+1C=3R

Two cylinders A and B fitted with pistons contain equal amounts of an ideal diatomic gas at 300 K. The piston of A is free to move while that of B is held fixed. The same amount of heat is given to the gas in each cylinder. If the rise in temperature of the gas in A is 30 K, then the rise in temperature of the gas in B is 

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Explanation

In both cylinders A and B the gases are diatomic (γ = 1.4). Piston A is free to move i.e. it is isobaric process. Piston B is fixed i.e. it is isochoric process. If same amount of heat ΔQ is given to both then

(ΔQ)isobaric=(ΔQ)isochoricμCp(ΔT)A=μCv(ΔT)B

(ΔT)B=CpCv(ΔT)A=γ(ΔT)A=1.4×30=42K.

Which of the following conditions is not characteristic of a reversible process?

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Explanation

According to the NCERT text, 'A reversible process proceeds infinitely slowly by a series of equilibrium states such that system and the surroundings are always in near equilibrium with each other.' It also states that 'A process is reversible only if it is quasi-static (...) and there are no dissipative effects.' Therefore, the presence of significant dissipative effects is not characteristic of a reversible process.

Why is a reversible process considered an idealised notion in thermodynamics?

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Explanation

The NCERT text states, 'From the preceding discussion, a reversible process is an idealised notion. A process is reversible only if it is quasi-static (system in equilibrium with the surroundings at every stage) and there are no dissipative effects.' These ideal conditions are rarely met in real-world processes, making it an idealised concept.

Which of the following phenomena is an example of an irreversible process?

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Explanation

The NCERT text explicitly states, 'The base of a vessel on an oven is hotter than its other parts. When the vessel is removed, heat is transferred from the base to the other parts, bringing the vessel to a uniform temperature... The process cannot be reversed; a part of the vessel will not get cooler spontaneously and warm up the base.' Options o1, o3, and o4 describe characteristics or examples of reversible processes.

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