Solutions MCQs for NEET — Chemistry Questions with Answers

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Mole of K2SO4 to be dissolved in 12 moles water to lower its vapour pressure by 10 mm of Hg at a temperature at which vapour pressure of pure water is 50 mm of Hg is

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Explanation

 

 

P-PsP=inin+N1050=3×n3×n+123n+12 = 15nn=1

Which has highest freezing point ?

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Explanation

Tf  is directly proportional to  number of ions

Lower is the effective molarity, higher is the freezing point.

Aluminium phosphate is 100% ionized in 0.01m aqueous solution. Hence, Tb/kb is

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Explanation

For AlPO4, i=2

TbKb=i × m =2×0.01=0.02

Which solution has highest freezing point?

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Explanation

Higher is the molar mass, lesser is the effective molarity. So, 1% sucrose solution has highest freezing point.

Osmotic pressure of 40% (w/V) urea solution is 1.64 atm. and that of 3.42% (w/V) cane sugar solution is 2.46 atm. When equal volumes of the above two solutions are mixed, the osmotic pressure of the resulting solution will be?  

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Explanation

π= π1+π2 , if equal volume are mixed volume of solution become double.

20g of naphthoic acid (C11H8O2) dissolved in 50g of benzene (Kf=1.72 K Kg mol-1) shows a depression in freezing point of 2K. The Vant Hoff factor is?

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Explanation

Mol. wt. of naphthoic acid=172

ΔTcal=1000 x 1.72 x 20 /50 x 172 = 4

i=experimentalΔTf=2/4=0.5
    calculated  ΔTf

A 0.002 molar solution of NaCl having degree of dissociation of 90% at 270C, has osmotic pressure equal to:-

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Explanation

α = i-1/n-1

0.9 = i-1/2-1

i=1.9

π=iCRT = 1.9x0.002x0.082x300

=0.094 bar

 

 

 

The density of NH4OH solution is found to be 0.6 g/ml. It contains 35% by mass of NH4OH. The normality of the solution is

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Explanation

dsol=    mass 
          volume

 

vsol= 100   ml
         0.6

 

N= W   X    1   
       E       V(L)

 

N= 35 1000 x 0.6 
        35          100

 

N = 6

The relative lowering of vapour caused by dissolving 71.3g of a substance in 1000g of water is 7.13x10-3. The molecular mass of substance is:-

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Explanation

P/P0 = nB/nA

7.13x10-3=71.3x18/mBx1000

msolute = 180

Total vapour pressure of mixture of 1 mol A(p0A = 150 torr) and 2 mol B(P0B = 240 torr) is 200 torr. In this case:-

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Explanation

P = P0AXA + P0BXB

P = 150(1/3)+240(2/3)

P = 210 torr

Pexp. < Pca; Negative derivation from Raoult's law

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